"Then there is the Ol Army story, cleaned and stored brass 'in the old days' turned black, and when cleaning and 'pickling' brass in the Ol Army days time was a factor, the factor of time was 'for a maximum of 2 minutes'."
Sure, time is a factor for any large organization. So far as I know, the army never 'cleaned, pickled and stored old brass' but they did do a LOT of experimental shooting and reloading that required cleaned cases. I've never seen any military time limit on the arsenal's vinegar based cleaning solution nor any reason to think there should be a time limit due to chemical reaction and I doubt you have either.
Anyone wanting to see what a few days soak in pure vinegar (the highest possible strength) does should try it on a couple of cases for themselves, not listen to me or any other self styled 'web expert'. Drop 'em in, take 'em out when you wish; then flush, dry and tumble 'em, load 'em (with a mild load if you're apprehensive) and see how they work. I think you'll find they look and perform same as any others. ??