Here are the values, based on a pressure temperature curve I found online for lead (a scan of an academic book).
I found an OSHA letter stating the max lead concentration for an indoor range is 50 micrograms per cubic meter (this should be the PEL, permissible exposure limit, based on breathing this for an 8 hour shift).
At lead's melting point (621F) the vapor pressure is 4X10^-7 Pa (400 parts per trillion)
@815F its 1X10^-4 Pa (1 part per billion)
@1300F it is 1Pa (10 ppm)
So, at 815F that is 12 micrograms per cubic meter, at the molten leads SURFACE, 1/4 of OSHA's PEL (and you KNOW they are conservative!)
800 would be a good casting temperature. At 1300 it would be significantly higher, 10,000 times higher actually.
870 degrees - 5X10^-4 Pa - 60 micrograms per cubic meter (just above OSHA PEL)
925 - 1X10^-3 Pa - 125 micrograms per cubic meter (2.5 times OSHA's limit for an 8 hour shift).
1000 - .01 PA (.1 ppm) = 1200 micrograms per cubic meter.
1100 (Added in on the edit just because this value was mentioned above) - .13 PA - 15,600 micrograms per cubic meter, three hundred times the OSHA guidelines.
The academic book I found the vapor pressure temperature curve at:
http://books.google.com/books?id=S20...ead"&f=false
While I have no qualms casting indoors, I base than on NOT going above 800 degrees. Telling people 1000 degrees is no big deal is not just wrong, but it is irresponsible as it is TWENTY FOUR times osha's permissible exposure limit.
To be fair, the vapor pressure concentration is at the surface of the molten lead. The vapor will slowly permeate the room, but would take a long time for the entire room to reach the above levels.
I am well familiar with Pascals. In fact, if you double check, I gave the partial pressure IN pascals. I then converted that to parts per million (which is easy to do since we know that we are usually close to 1 atmosphere of pressure), and I think I even gave the disclaimer that yes, that is at the molten leads surface and that it will take some time for it to disperse around the room.
Quote:
Originally Posted by Spudgunr
1000 - .01 PA (.1 ppm)
See, .01Pa (ok, I capitalized the A when I shouldn't have, my bad).
Quote:
Originally Posted by Spudgunr
To be fair, the vapor pressure concentration is at the surface of the molten lead. The vapor will slowly permeate the room, but would take a long time for the entire room to reach the above levels
And again, my disclaimer saying that the concentrations would be at the surface of the molten lead.
Quote:
Originally Posted by MtGun44
IIRC, the vapor pressure is very, very low at any remotely resonable melt temperature,
like a fraction of 1 mm of mercury (a pressure measurement; 760 mm of Hg represents
normal sea level air pressure of 14.7 psi)
And even a fraction of 1mm of mercury is a whole lot of parts per million. Just because the number is small doesn't mean it is benign.
I was TRYING to be screaming when I mentioned a number that is 60 times OSHA's PEL, that was previously stated to have no lead vapors, indicating that there is no harm in it. While I will be respectful, I will NOT be polite when it comes to matters that are clearly dangerous. Safety must be emphasized. If I were in the reloading area and somebody stated that you could just swap components and keep the same charge I would likewise be "yelling" (emphasizing with bold and large font).
Would anybody else now like to de-emphasize the point that lead DOES make vapors at a considerable level not much above our working temperatures? Again, I've made the personal decision to cast indoors, but not at super high temperatures, because I can see by the math once you start getting up above 800 degrees the lead vapors go up quick.
I forgot that I had looked up other temperatures and vapor pressures:
My 12 micrograms per cubic meter was actually based on 815 degrees, not 800
870 degrees - 60 micrograms per cubic meter (just above OSHA PEL)
925 - 125 micrograms per cubic meter
Vapor pressure is expotential, so I would avoid going over 870 degrees for any length of time. But, the way vapor pressure works, that concentration is at the source of the lead. It would take a long time to get your whole garage up to that concentration.
Source: Osha's PEL, and I majored in chemical engineering. It just took me a while to find the reference for lead's vapor pressure curve (I had looked multiple times, took a while to find it, the above numbers are based on what I did find, source to be provided later).
If you guys want a little more science to it, here is my research that has convinced me I'm safe casting indoors (garage) with no door open. I don't do a TON of casting, if I did I MAY get a little vent fan to go out the window. I'm looking at a kitchen fume hood, connected to a dryer vent flex hose to throw out the window. But, until then, I feel safe.
I found an OSHA letter stating the max lead concentration for an indoor range is 50 micrograms per cubic meter (this should be the PEL, permissible exposure limit, based on breathing this for an 8 hour shift).
At lead's melting point (621F) the vapor pressure is 4X10^-7 Pa (400 parts per trillion)
@800F its 1X10^-4 Pa (1 part per billion)
@1300F it is 1Pa (10 ppm)
So, at 800F that is 12 micrograms per cubic meter, at the molten leads SURFACE, 1/4 of OSHA's PEL (and you KNOW they are conservative!)
800 would be a good casting temperature. At 1300 it would be significantly higher, 10,000 times higher actually.
So, dont melt on a turkey fryer and let it get SUPER heated. You are fine at normal casting temperatures. Of course, that is an outdoor operation regardless due to all the **** in wheel weights.
BTW: Zinc melts at less than 800F. If you haven't melted your zinc wheel weights you haven't exceeded that temperature.
Based on the math I have no qualms about casting in the garage.