I've shot a few of their loads in 7.62x39, .270 Win, and 7.7x58 (Hornady branded).
I also use their brass in 9x19mm, 7.62x54R, and {the third cartridge escapes me, at the moment}.
The 9x19mm is so-so.
The 7.62x39 seemed to be on par with the Remington brass I had to compare it to.
The .270 stuff was fine. -Nothing special, but not bad, either.
The 7.7x58 was as fine. -Nothing special, but having actual 7.7x58 case dimensions without forming from 30-06 was nice.
The 7.62x54R, I like quite a bit. Mine is stamped "Winchester", but it is drawn by Prvi - on the same machines they use for their own brass. Good stuff.
While I admit that all manufacturers can put out a bad product... I would be headspacing that .308 before I dug any deeper. Nothing should be blowing primers with a factory chamber. If it's not factory (not likely, but possible), then I blame the shooter. He should have known about his short throat/tight throat/etc, and not stuffed factory ammo into it without checking the specs.
The only thing that I've seen some rifles have issues with while shooting PPU ammo is primers. Prvi uses extremely hard primer cups. Rifles that have weak firing pin/striker springs sometimes can't set them off without multiple strikes.
The way things have been going lately, I'll take PPU brass over S&B, PMC, or even Fiocchi any day.