Did this occur shooting single-action (SA), double-action (DA), or both?
The timing on a S&W revolver is mostly regulated by the cylinder stop, the little nub sticking out of the bottom of the cylinder window, just above the trigger. It engages cylinder stop notches in the cylinder. Here's how to check it.
SA: Verify that the revolver is unloaded; do NOT put snap caps or empty cases in the chambers. Cock the revolver, drop the hammer, and hold the trigger down. Grasp the cylinder gently with your thumb and forefinger and turn it slightly in both directions with a wiggling motion. Repeat for all 6 chambers.
Cylinder is stationary or wiggles an imperceptible amount from side to side: GOOD. Cylinder freely turns in one direction, but when you turn it in the other direction, you hear a "tick" and then it stops: BAD. (This indicates that the cylinder stop is not lined up with the stop notch when the hammer drops.) Cylinder wiggles a noticeable amount from side to side, far enough that you can really see it: BAD. (Excess cylinder stop wear.)
DA: This is a little trickier. Verify that the revolver is unloaded; do NOT put snap caps or empty cases in the chambers. Sloooowly draw the trigger back while holding the cylinder next to your ear. You should hear the "tick" of the cylinder stop engaging right before the hammer falls. Hold the trigger down and repeat the SA tests. NOTE: You may need to repeat the test several times because the stop notch engagement point is so close to the point when the hammer drops that it's hard to draw the trigger back slowly enough to hear the difference.
Good luck!