Federal's Catalyst lead-free primers are based on bismuth-oxide rather than DDNP.
As for Fiocchi, the current iteration of their products is about two or three years old. Fiocchi had other generations of lead free primer quite a few years before that.
I do not have data to indicate a similar comparison to lead-styphnate for accuracy. I do know that Italian forces use the Fiocchi ZP (lead-free) and they do not have any problems with full auto. They have been accepted for NATO stockpiles. If I was shooting benchrest, they'd have to be proven for that, but I think for most people the volume of shooting happens with handgun cartridges.
Fiocchi claims a 15-year shelf life, which may be less than lead styphnate, but more than long enough for any of us to shoot with. Bear in mind that is the claimed shelf life which is almost certainly very conservative. They will probably last a lot longer. If someone desires ammo for long-term storage, use lead-styphnate, but there's no reason to shoot those.
As for reliability in ignition, I have had one failure in about 5000 with Fiocchi and it was probably because I damaged the anvil with a double-feed in the hand priming tool. I have no concerns about reliability at all, especially for ammunition that I intend to shoot for training and practice. If someone wanted more proven ammo for carry, I suggest factory ammo. But for reloads, days at the range, practice, training classes, etc., I can't see a reason not to love the lead-free.
I have not shot Catalyst, but if Federal made them available as a component I would try them immediately and unless there was a serious problem, I'd most likely adopt them. For me, that would mean buying about 20,000 and 5 to 10 thousand more per year. I understand that for Vista that doesn't mean anything, but I would hope that most reloaders do the same for all the good reasons there are.