So does the ratio matter could I mix it however I wanted to if I did? or can you only use a small portion of one to the other?
The single most important thing to remember when shooting black powder is to be consistent. That is, once you've determined what load works best for your particular gun, ALWAYS load the same materials the same way each time.
Now, applying that to your question: yes, the ratio matters. Changing the ratio will change the maximum pressure reached and the amount of time it takes to reach that maximum, which in turn will affect the velocity, energy and flight path characteristics of the projectile. In short, everything having to do with accuracy. How much it changes depends on how much the ratio changed.
Is one ratio "more accurate" than the other? Perhaps, but not necessarily. It's just different, and once you've determined how to shoot the gun with one "ratio", changing that ratio will affect (maybe a little and maybe a lot) the results and you won't be hitting where you're aiming.